Product ID:ROYAL BLUE MET, 14790D
MSDS Date:05/14/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLQFY

E.I. DUPONT DE NEMOURS & CO., (INC.) AUTOMOTIVE

WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637

Info Phone: 800-441-7515/800-441-3637

Cage: UO015

E.I. DUPONT DE NEMOURS & CO., (INC.) AUTOMOTIVE

WILMINGTON, DE 19898 US

Telephone: 800-441-7515/800-441-3637

Cage: UO015

MEDIUM MINERAL SPIRITS

CAS: 64742-88-7

OSHA PEL NONE

ACGIH TLV: NONE

1,2,4-TRIMETHYL BENZENE

CAS: 95-63-6

RTECS: DC3325000

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

CUMENE

CAS: 98-82-8

RTECS: GR8575000

OSHA PEL 50 PPM (SKIN)

ACGIH TLV: 50 PPM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

AROMATIC HYDROCARBON

CAS: 64742-95-6

RTECS: WF3400000

OSHA PEL NONE

ACGIH TLV: NONE

LEAD NAPHTHENATE

CAS: 61790-14-5

RTECS: QK9150000

OSHA PEL 50.0 UG/M3 (LEAD)

ACGIH TLV: 150.0 UG/M3 (LEAD)

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM; C 300 PPM

ACGIH TLV: 50 PPM (SKIN)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

VM&P NAPHTHA

CAS: 64742-89-8

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

NAPHTHALENE

CAS: 91-20-3

RTECS: OJ0525000

OSHA PEL 50 MG/M3;10 PPM

ACGIH TLV: 52 MG/M3;10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

AROMATIC HYDROCARBON

CAS: 64742-94-5

RTECS: WF3100000

OSHA PEL NONE

ACGIH TLV: NONE

ALKYD RESIN

CAS: 66070-61-9

OSHA PEL NONE

ACGIH TLV: NONE

PHTHALOCYANINE BLUE PIGMENT

CAS: 147-14-8

RTECS: GL8510000

OSHA PEL 1MG/M3 (CU)

ACGIH TLV: 1MG/M3 (CU)

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE NOSE AND THROAT
IRRITATION. MAY CAUSE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY
THE FOLLOWING PROGRESSIVE STEPS: HEADACHE, DIZZINESS, NAUSEA,
STAGGERING GAIT, CONFUSION, UNCONSC IOUSNESS. REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. SKIN OR EYE CONTACT:
MAY CAUSE IRRITATION OR BURNING OF THE EYES. REP EATED OR PROLONGED
LIQUID CONTACT MAY CAUSE SKIN IRRITATION WITH DISCOMFORT AND
DERMATITIS. CONTAINS TOLUENE AND LEAD NAPHTHENATE WHICH ARE LISTED
AS NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK (SIGNS &
SYMPTOMS OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT):
CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING
LATEST HEALTH HAZARD AND EXPOSURE INFORMATION . OTHER POTENTIAL
HEALTH HAZARDS INCLUDE: ME DIUM MINERAL SPIRITS: LABORATORY STUDIES
WITH RATS HAVE SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY
DAMAGE AND KIDNEY OR LIVER TUMORS. THESE EFFECTS WERE NOT SEEN IN
SIMILAR STUDIES WITH GUINEA PIGS, DOGS, OR MONKEYS. SEVERAL
STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT
INCREASE OF KIDNEY DAMAGE OR AN INCREASE IN KIDNEY OR LIVER TUMORS.
XYLENE: RECURRENT OVEREXPOSURE MA Y RESULT IN LIVER (TOXICOLOGICAL
INFO)
Medical Cond Aggravated by Exposure:TOLUENE: INDIVIDUALS WITH
PREEXISTING DISEASES OF THE CENTRAL NERVOUS SYSTEMMAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
XYLENE: INDIVIDUALS (SUPPLEMENTAL SAFETY AND HEALTH)

First Aid:INHALATION: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST,
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION,
PREFERABLY MOUTH-TO-MOUTH. IF BREATHING DIFFICULTY PERSISTS, OR
OCCURS LATER, CONSULT A PHYSICIAN. SKIN OR EYE: IN CASE OF
CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES; CALL A PHYSICIAN. IN CASE OF SKIN CONTACT, WASH WITH SOAP
AND WATER. IF I RRITATION OCCURS, CONTACT A PHYSICIAN. INGESTION:
GASTRO-INTESTINAL DISTRESS. IN THE UNLIKELY EVENT OF INGESTION,
CALL A PHYSICIAN IMMEDIATELY AND HAVE NAMES OF INGREDIENTS
AVAILABLE.

Flash Point Method:CC
Flash Point:=22.8C, 73.F
73F - BELOW 100F
Lower Limits:.8% APPROX.
Upper Limits:7.0% APPROX.
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT, INCLUDING
SELF-CONTAINED BREATHING APPARATUS (NIOSH APPROVED - ), IS
RECOMMENDED. WATER FROM FOG NOZZLES MAY BE USED TO PREVENT PRESSURE
BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASHPOINT, EMITS
FLAMMABLE VAPORS WHICH, WHEN MIXED WITH AIR, CAN BURN OR BE
EXPLOSIVE. FINE MIST OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES
BELOW THE FLASH POINT.

Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT AND BREATHING OF VAPOR. CONFINE AND REMOVE
WITH INERT ABSORBENT.

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND
CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120 DEG F.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING
WITHOUT A NIOSH APPROVED RESPIRATOR APPROPRIATE VENTILATION.

Respiratory Protection:WEAR A PROPERLY FITTED AIR PURIFYING RESPIRATOR
(NIOSH APPROVED - ) WITH ORGANIC VAPOR CARTRIDGES (NIOSH APPROVED
TC-23C) AND PARTICULATE FILTER (NIOSH TC-84A) DURING APPLICATION
AND UNTIL VAPORS AND SPRAY MISTS ARE EXHAUSTED. FOLLOW THE
RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO
KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS AND OTHER
APPLICABLE EXPOSURE LIMITS.
Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . COVERALLS ARE RECOMMENDED. PROTECTIVE CREAMS:
DO NOT USE FOR PROTECTION. MAY BE USED FOR EASE OF CLEAN UP.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING. DO NOT BREATHE VAPORS OR MISTS.
Supplemental Safety and Health
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE (CONT): WITH PRE-EXISTING
DISEASE OF THE CENTRAL NERVOUS SYSTEM, KIDNEYS, LIVER,
CARDIOVASCULAR SYSTEM, LUNGS, OR BONE MARROW MAY HAVE INCREASED
SUSCEPTIBILIT Y TO THE TOXICITY OF EXCESSIVE EXPOSURES.
NAPHTHALENE: INDIVIDUALS WITH PREEXISTING DISEASES OF THE (STATE
REGULATORY)

Boiling Pt:=100.C, 212.F
B.P. Text:APPROX 100-213 DEG C.
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SYSTEM IN WATER
Appearance and Odor:LIQUID. ODOR: NOT SPECIFIED BY MFR .
Percent Volatiles by Volume:66.2

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Hazardous Decomposition Products:CO, CO2, SMOKE, OXIDES OF HEAVY
METALS.

Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Toxicological Information:N/P. SIGNS AND SYMPTOMS OF
OVEREXPOSURE (CONT): AND KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE
PRODUCED IRREGULAR HEARTBEATS IN ANIMALS AND OCCASIONAL
PALPATATIONS IN HUMANS. RATS EXPOSED TO VER Y HIGH AIRBORNE LEVELS
HAVE EXHIBITED HIGH FREQUENCY HEARING DEFICITS. THE SIGNIFICANCE OF
THIS TO MAN IS UNKNOWN. CHROMOSOMAL CHANGES IN THE CIRCULATING
BLOOD OF EXPOSED WORKERS HAVE BEEN REPORTED. T HE SIGNIFICANCE OF
THESE REPORTS IS UNCLEAR BECAUSE OF EXPOSURE TO OTHER SUBSTANCES.
XYLENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER AND KIDNEY
INJURY. CAN BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS.
CANADA (ECOLOGICAL INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:N/P. TOXICOLOGICAL INFO (CONT): CLASSIFIES XYLENE AS A
DEVELOPMENTAL TOXIN AS HIGH EXPOSURES TO XYLENE IN SOME ANIMAL
STUDIES HAVE BEEN REPORTED TO CAUSE HEALTH EFFECTS ON THE
DEVELOPING FETUS / EMBRYO. THESE EFFECTS WERE OFTEN AT LEVELS
TOXIC TO THE ADULT ANIMAL. THE SIGNIFICANCE OF THESE EFFECTS TO
HUMANS IS NOT KNOWN. AROMATIC HYDROCARBON: LABORATORY STUDIES WITH
RATS HAVE SHOWN THAT PET ROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE
AND KIDNEY OR LIVER TUMORS. THESE EFFECTS WERE NOT SEEN IN SIMILAR
STUDIES WITH GUINEA PIGS, DOGS, OR MONKEYS. SEVERAL STUDIES
EVALUATING PETROLEUM WORKERS H AVE NOT SHOWN A (TRANSPORT INFO)

Transport Information:N/P. ECOLOGICAL INFO (CONT): SIGNIFICANT
INCREASE OF KIDNEY DAMAGE OR AN INCREASE IN KIDNEY OR LIVER TUMORS.
NAPHTHALENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER AND KIDNEY
INJURY. AROMATIC HYDROCARBON: LABORATORY STUDIES WITH RATS HAVE
SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE AND KIDNEY
OR LIVER TUMORS. THESE EFFECTS WERE NOT SEEN IN SIMILAR STUDIES
WITH GUINEA PIGS, DOG S, OR MONKEYS. SEVER STUDIES EVALUATING
PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT INCREASE OF KIDNEY
DAMAGE OR AN INCREASE IN KIDNEY OR LIVER TIMORS. LEAD NAPHTHENATE:
OVEREXPOSURE TO LEAD MAY C AUSE ADVERSE EFFECTS TO THE (SARA III)

SARA Title III Information:SUPPLIER 313 NOTIFICATION: THE CHEMICALS
LISTED (IN THE INGREDIENTS SECTION) WITHE PERCENTAGES (TOLUENE,
1,2,4-TRIMETHYL BENZENE, XYLENE, CUMENE, NAPHTHALENE, AND LEAD
NAPHTHENATE) ARE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION
313 OF THE EMERGENCY PLANNING AND RIGHT-TO-KNOW ACT OF 1986 AND OF
40 CFR 372. TRANSPORT INFO (CONT): BLOOD FORMING, NERVOUS,
URINARY, REPRODUCTIVE SYSTEMS INC LUDING EMBRYOTOXIC EFFECTS.
SYMPTOMS MAY INCLUDE LOSS OF APPETITE, ANEMIA, DISTURBANCES OF
SLEEP AND FATIGUE. SEE OSHA LEAD STANDARD 29 CFR 1910.1025. FOR
EXPOSURES LONGER THAN 8 HOURS THE OSHA EXPOSU RE LIMIT IS REDUCED
(FEDERAL REGULATORY)
Federal Regulatory Information:OSHA NAME: FLAMMABLE LIQUID. SARA
III (CONT): BY THIS FORMULA: LIMIT (IN UG / M3) = 400 / HOURS
WORKED IN THE DAY. CAN BE ABSORBED THROUGH THE SKIN IN HARMFUL
AMOUNTS. VM&P NAPHTHA: LABORATORY STUDIES WITH RATS HAVE SHOWN
THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE AND KIDNEY OR
LIVER TUMORS. THESE EFFECTS WERRE NOT SEEN IN SIMILAR STUDIES WITH
GUINEA PIGS, DOGS, OR MONKEYS. SEVERAL STUDIES EVALUATING
PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT INCREASE OF KIDNEY
DAMAGE OR AN I NCREASE IN KIDNEY OR LIVER TUMORS.
State Regulatory Information:TOLUENE: WARNING: THIS CHEMICAL IS KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. LEAD NAPHTHENATE: WARNING: THIS CHEMICAL IS
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS
OR OTHER REPRODUCTIVE HARM. SUPPLEMENTAL SAFETY AND HEALTH
(CONT): LIVER OR KIDNEYS MAY HAVE INCREASED SUSCEPTIBILITY TO THE
TOXICITY OF EXCESSIVE EXPOSURES.